The ultrasonic testing has been considered a promising method for diagnosing and characterizing masonry walls. As ultrasonic waves tend to travel faster in denser materials, their use is common in evaluating the conditions of various materials. Presence of internal voids, e.g., would alter the wave path, and this distinct behavior could be employed to identify unknown conditions within the material, allowing for the assessment of its condition. Therefore, we applied mixed models and Gaussian processes to analyze the behavior of ultrasonic waves on masonry walls and identify relevant factors impacting their propagation. We observed that the average propagation time behavior differs depending on the material for both models. Additionally, the condition of the wall influences the propagation time. Gaussian process and mixed model performances are compared, and we conclude that these models can be useful in a classification model to automatically identify anomalies within masonry walls.