Abstract: Particulate matter smaller than 2.5 microns (PM2.5) is a com monly measured parameter in ground-based sampling networks designed to assess short and long-term air quality. The measurement techniques for ground based PM2.5 are relatively accurate and precise, but monitoring lo cations are spatially too sparse for many applications. Aerosol Optical Depth (AOD) is a satellite based air quality measurement that can be computed for more spatial locations, but measures light attenuation by particulates throughout in entire air column, not just near the ground. The goal of this paper is to better characterize the spatio-temporal relationship between the two measurements. An informative relationship will aid in imputing PM2.5 values for health studies in a way that accounts for the variability in both sets of measurements, something physics based models cannot do. We use a data set of Chicago air quality measurements taken during 2007 and 2008 to construct a weekly hierarchical model. We also demonstrate that AOD measurements and a latent spatio-temporal process aggregated weekly can be used to aid in the prediction of PM2.5measurements.
Abstract: An analysis of air quality data is provided for the municipal area of Taranto characterized by high environmental risks, due to the massive presence of industrial sites with elevated environmental impact activities. The present study is focused on particulate matter as measured by PM10 concentrations. Preliminary analysis involved addressing several data problems, mainly: (i) an imputation techniques were considered to cope with the large number of missing data, due to both different working periods for groups of monitoring stations and occasional malfunction of PM10 sensors; (ii) due to the use of different validation techniques for each of the three monitoring networks, a calibration procedure was devised to allow for data comparability. Missing data imputation and calibration were addressed by three alternative procedures sharing a leave-one-out type mechanism and based on ad hoc exploratory tools and on the recursive Bayesian estimation and prediction of spatial linear mixed effects models. The three procedures are introduced by motivating issues and compared in terms of performance.